Vol 10: 4-Hydroxy-6-alkyl-2-pyrones as nucleophilic coupling partners in Mitsunobu reactions and oxa-Michael additions.Reportar como inadecuado



 Vol 10: 4-Hydroxy-6-alkyl-2-pyrones as nucleophilic coupling partners in Mitsunobu reactions and oxa-Michael additions.


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This article is from Beilstein Journal of Organic Chemistry, volume 10.AbstractTwo mild and efficient strategies have been developed for the O-functionalisation of 4-hydroxy-6-alkyl-2-pyrones, by using them as nucleophilic partners in oxa-Michael additions and the Mitsunobu reaction. The reactions proceed in moderate to excellent yields on a range of substrates containing useful functionality. The reactions serve as practical and valuable synthetic methods to construct complex 2-pyronyl ethers, which are found embedded in a number of natural products.



Autor: Burns, Michael J; Ronson, Thomas O; Taylor, Richard J K; Fairlamb, Ian J S

Fuente: https://archive.org/



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