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Hussein M. H. Alhendawi ; Olga Juanes ; Carlos Rodríguez-Ubis ;Journal of the Mexican Chemical Society 2009, 53 (3)

Autor: Ernesto Brunet

Fuente: http://www.redalyc.org/


Introducción



Journal of the Mexican Chemical Society ISSN: 1870-249X editor.jmcs@gmail.com Sociedad Química de México México Brunet, Ernesto; Alhendawi, Hussein M.
H.; Juanes, Olga; Rodríguez-Ubis, Carlos The Quest for Relationships between Conformation and Chiroptical Properties: From Solution to Solid State Journal of the Mexican Chemical Society, vol.
53, núm.
3, julio-septiembre, 2009, pp.
155-162 Sociedad Química de México Distrito Federal, México Available in: http:--www.redalyc.org-articulo.oa?id=47512154013 How to cite Complete issue More information about this article Journals homepage in redalyc.org Scientific Information System Network of Scientific Journals from Latin America, the Caribbean, Spain and Portugal Non-profit academic project, developed under the open access initiative Article J.
Mex.
Chem.
Soc.
2009, 53(3), 155-162 © 2009, Sociedad Química de México ISSN 1870-249X The Quest for Relationships between Conformation and Chiroptical Properties: From Solution to Solid State Ernesto Brunet*, Hussein M.H.
Alhendawi, Olga Juanes, and Juan Carlos Rodríguez-Ubis Departamento de Química Orgánica, Facultad de Ciencias.
Universidad Autónoma de Madrid, 28049-Madrid. e-mail: ernesto.brunet@uam.es Dedicated to the late Prof.
Ernest Ludwig Eliel in memoriam Received July 15, 2009; accepted September 14, 2009 Abstract.
The enormous interest of the late Prof.
Ernest Ludwig Eliel for stereochemical problems has led not only to his publication of a impressively long list of papers, books and countless invitations for keynote lectures at conferences, but has stimulated a similar interest in this field among the many who have had the opportunity to work with him.
Ernest’s seed on one of us turn out in the quest for new relationships between conformation and chiroptical properties. The germ was a simple molecule, cis-3-hydroxythiane S-oxide, that enabled us to show that the specific rotation at any position of its conformational equilibrium is a weighte...





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