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Abstract : Ab initio calculations of the second-order effects of the configuration interaction on the orbit-dependent magnetic-hyperfine-structure parameters in the 3dN 4s2 configuration have been performed. The importance of the contributions of the different excitations is discussed and a comparison is made between Sc and Ti. The ratio α = a1-a sC is found to be 1.07 and 1.05 in Sc and Ti respectively.

Keywords : atomic electron correlations atomic hyperfine structure scandium titanium Sc I Ti I configuration interaction 3d sup N 4s sup 2 configuration second order effects orbit dependent magnetic hyperfine structure parameters





Autor: C. Bauche-Arnoult J.-J. Labarthe

Fuente: https://hal.archives-ouvertes.fr/



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