Influence of TiO2 Nanocrystals Fabricating Dye-Sensitized Solar Cell on the Absorption Spectra of N719 SensitizerReportar como inadecuado




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International Journal of PhotoenergyVolume 2012 2012, Article ID 906198, 7 pages

Research Article Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, 1 Gaoxin Road, Shaanxi, Baoji 721013, China

Received 9 April 2012; Accepted 22 May 2012

Academic Editor: Mohamed Sabry Abdel-Mottaleb

Copyright © 2012 Puhong Wen et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The absorption spectra of N719 sensitizer anchored on the films prepared by TiO2 nanocrystals with different morphology and size were investigated for improving the performance of dye-sensitized solar cell DSC. We find that the morphology and size of TiO2 nanocrystals can affect the UV-vis and FT-IR spectra of the sensitizer anchored on their surfaces. In particular, the low-energy metal-to-ligand charge-transfer transitions MLCT band in the visible absorption spectra of N719 is strongly affected, and locations of these MLCT bands revealed larger differences. The results indicate that there is a red shift of MLCT band in the spectra obtained by using TiO2 nanocrystals with long morphology and large size compared to that in solution. And it produced a larger red-shift on the MLCT band after TiO2 nanocrystals with small size mixed with some long nanocrystals. Accordingly, the utilization rate to visible light is increased. This is a reason why the DSC prepared by using such film as a photoelectrode has better performance than before mixing.





Autor: Puhong Wen, Yinfeng Han, and Weixing Zhao

Fuente: https://www.hindawi.com/



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