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Journal of NanotechnologyVolume 2012 2012, Article ID 709031, 6 pages

Research Article

Department of Electrical and Computer Engineering, University of Delaware, 140 Evans Hall, Newark, DE 19716, USA

Département de Génie Électrique, École de Technologie Supérieure, 1100 rue Notre-Dame Ouest, Montréal, QC, Canada H3C1K3

Received 21 November 2011; Revised 7 February 2012; Accepted 15 February 2012

Academic Editor: Sharad D. Bhagat

Copyright © 2012 Fan Xu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

We present a simple method for the fabrication of an interconnected porous T i O 2 nanostructured film via dip coating in a colloidal suspension of ultrathin T i O 2 nanowires followed by high-temperature annealing. The spheroidization of the nanowires and the fusing of the loosely packed nanowire films at the contact points lead to the formation of nanopores. Using this interconnected T i O 2 nanowire network for electron transport, a PbS- T i O 2 heterojunction solar cell with a large short-circuit current of 2.5 mA-cm

, a 𝑉 o c of 0.6 V, and a power conversion efficiency of 5.4% is achieved under 8.5 mW-cm

white light illumination. Compared to conventional planar T i O 2 film structures, these results suggest superior electron transport properties while still providing the large interfacial area between PbS quantum dots and T i O 2 required for efficient exciton dissociation.





Autor: Fan Xu, Jaime Benavides, Xin Ma, and Sylvain G. Cloutier

Fuente: https://www.hindawi.com/



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