DIRECT OBSERVATION OF THE TRANSITION STATE OF A PHOTOCHEMICAL REACTION ; THE Hg3 P1, Cl2 SYSTEMReportar como inadecuado




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Abstract : A novel method designed to observe the collision complex of a photochemical reaction is reported here. The reactants Hg, Cl2 are frozen in a van der Waals complex Hg-Cl2, and then promoted by an optical excitation 250 nm to the reactive state. The broad complex action spectrum, presumably due to the Hg+-Cl-2 intermediate, is monitored through the HgCl B2Σ+ fluorescence.





Autor: C. Jouvet B. Soep

Fuente: https://hal.archives-ouvertes.fr/



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