Dehydrosulfurization of Aromatic Thioamides to Nitriles Using IndiumIII TriflateReportar como inadecuado




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The efficient dehydrosulfurization of thioamides to nitriles was carried out using indiumIII triflate as a catalyst. Based on the results of the initial study, the optimal reaction conditions required 5 mol% of indiumIII triflate with toluene as the practical solvent. Various thioamides were successfully converted to nitriles in high yields.

KEYWORDS

IndiumIII Triflate, Dehydrosulfurization, Thioamide, Nitriles

Cite this paper

Mineno, T. , Takebe, Y. , Tanaka, C. and Mashimo, S. 2014 Dehydrosulfurization of Aromatic Thioamides to Nitriles Using IndiumIII Triflate. International Journal of Organic Chemistry, 4, 169-173. doi: 10.4236-ijoc.2014.43018.





Autor: Tomoko Mineno, Yu Takebe, Chiaki Tanaka, Sho Mashimo

Fuente: http://www.scirp.org/



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