Synthesis and Photochemical Cyclization of a Novel Enyne-CarbodiimideReportar como inadecuado




Synthesis and Photochemical Cyclization of a Novel Enyne-Carbodiimide - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

1

FB 8 - OC1 Chemie und Biologie, Universität Siegen, Adolf-Reichwein-Strasse, D-57068 Siegen, Germany

2

Present address: Facultad de Química, Universidad de Santiago de Compostela, Spain





*

Author to whom correspondence should be addressed.



Abstract The triplet sensitized cyclization of enyne-carbodiimide 4 leads to efficient formation of indoloquinoline 5 with concomittant loss of a methyl group. The efficient loss of the methyl group was explained using AM1 semiempirical calculations.

Keywords: Carbodiimides; diradicals; enynes; photocyclization; triplet Carbodiimides; diradicals; enynes; photocyclization; triplet





Autor: Michael Schmittel 1,* , David Rodríguez 1,2 and Jens-Peter Steffen 1

Fuente: http://mdpi.com/



DESCARGAR PDF




Documentos relacionados