Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper I-copper II Complex: {Bisethylenediamine Copper II Bisdiiodocuprate I}Reportar como inadecuado




Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper I-copper II Complex: {Bisethylenediamine Copper II Bisdiiodocuprate I} - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

1

Department of Chemistry, School of Science, Azzahra University, P.O.Box 1993891176, Tehran, Iran

2

Institute and Outpatient Clinic for Occupation and Social Medicine of the Justus-Liebig-University of Giessen, Aulweg 129 III, 35392 Giessen, Federal Republic of Germany





*

Author to whom correspondence should be addressed.



Abstract A novel, mixed-valent copperI-copperII complex, {bisethylene-diaminecopperII bisdiiodocuprateI} 1, has been prepared by electrochemicaldissolution of a sacrificial copper anode in a solution of ethylenediamine en, I2 andtetraethylammoniumperchlorate TEAP as supporting electrolyte in acetonitrile AcNand characterized by single-crystal X-ray structure determination. The crystal structure ofthe complex 1 shows that it consists of a CuI2 polymer formed from I- ligands bridgingCuI ions, with a nearly square planar geometry of bivalente CuII atoms chelated by twoethylenediamine ligands. The results also show that direct electrosynthesis of the complexhad high current efficiency, purity and electrolysis yield. View Full-Text

Keywords: Copper I-II; complex; electrosynthesis; ethylenediamine; diiodocuprateI. Copper I-II; complex; electrosynthesis; ethylenediamine; diiodocuprateI.





Autor: Lida Fotouhi 1,* , Saeed Dehghanpour 1, Majid M Heravi 1 and Mahboobeh Dashti Ardakani 2

Fuente: http://mdpi.com/



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