Unusual Reactivity Patterns of 1,3,6,8-Tetraazatricyclo-4.4.1.13,8-dodecane TATD Towards Some Reducing Agents: Synthesis of TMEDAReportar como inadecuado


Unusual Reactivity Patterns of 1,3,6,8-Tetraazatricyclo-4.4.1.13,8-dodecane TATD Towards Some Reducing Agents: Synthesis of TMEDA


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Departamento de Química, Universidad Nacional de Colombia, Carrera 30 No. 45-03, CiudadDepartamento de Química, Universidad Nacional de Colombia, Carrera 30 No. 45-03, Ciudad Universitaria, Bogotá, D.C., Colombia





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Author to whom correspondence should be addressed.



Abstract N,N,N ́,N ́-Tetramethylethylenediamine TMEDA can be synthesized by simple reduction of 1,3,6,8-tetraazatricyclo-4.4.1.1.3,8dodecane TATD, an aminal cage type amine, with formic acid. The aminal can be converted to TMEDA in high yield very easily and in a very short time. We comment on the scope and limitations of the reduction of thisaminal and propose a possible reaction mechanism. View Full-Text

Keywords: Aminals; TMEDA; aminal reduction; Leuckart-Wallach reaction Aminals; TMEDA; aminal reduction; Leuckart-Wallach reaction





Autor: Augusto Rivera * and Jaime Rios-Motta

Fuente: http://mdpi.com/



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