Aqueous TiIV-Catalyzed Diels-Alder ReactionReportar como inadecuado


Aqueous TiIV-Catalyzed Diels-Alder Reaction


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Applied Nanoworks, Inc. 9 University Place, Rensselaer, NY 12144, USA





Abstract The aqueous Diels-Alder reaction of 1,3-cyclohexadiene with 1,4-benzoquinone was compared and contrasted to the same reaction catalyzed with Flextyl P™, a novel TiIV performance catalyst. The catalyst improved conversion by 22% versus the uncatalyzed reaction and represents a rare example of a TiIV catalyzed Diels-Alder reaction in water. View Full-Text

Keywords: Diels-Alder reaction; aqueous; cyclohexadiene; benzoquinone; Lewis acid catalysis; green chemistry; water-soluble Lewis acid catalyst. Diels-Alder reaction; aqueous; cyclohexadiene; benzoquinone; Lewis acid catalysis; green chemistry; water-soluble Lewis acid catalyst.





Autor: Kyle E. Litz

Fuente: http://mdpi.com/



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