Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and ElectrolysisReportar como inadecuado




Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan





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Abstract One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.

Keywords: samarium diiodide; electrolysis; cyclization; hydrindanone samarium diiodide; electrolysis; cyclization; hydrindanone





Autor: Masakazu Sono * , Natsuko Ise, Tsutomu Shoji and Motoo Tori *

Fuente: http://mdpi.com/



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