Enantioselective Cycloaddition Reactions Catalyzed by BINOL-Derived Phosphoric Acids and N-Triflyl Phosphoramides: Recent AdvancesReportar como inadecuado




Enantioselective Cycloaddition Reactions Catalyzed by BINOL-Derived Phosphoric Acids and N-Triflyl Phosphoramides: Recent Advances - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

Department of Chemistry and Pharmacy, Organic Chemistry Chair I and Interdisciplinary Center for Molecular Materials, University of Erlangen-Nürnberg, Henkestrasse 42, Erlangen 91054, Germany





*

Author to whom correspondence should be addressed.



Academic Editor: Raquel P. Herrera

Abstract Over the last several years there has been a huge increase in the development and applications of new efficient organocatalysts for enantioselective pericyclic reactions, which represent one of the most powerful types of organic transformations. Among these processes are cycloaddition reactions e.g., 3+2; formal 3+3; 4+2; vinylogous 4+2 and 1,3-dipolar cycloadditions, which belong to the most utilized reactions in organic synthesis of complex nitrogen- and oxygen-containing heterocyclic molecules. This review presents the breakthrough realized in this field using chiral BINOL-derived phosphoric acids and N-triflyl phosphoramide organocatalysts. View Full-Text

Keywords: cycloaddition reactions; BINOL-derived phosphoric acids; N-triflyl phosphoramides; enantioselective pericyclic reactions cycloaddition reactions; BINOL-derived phosphoric acids; N-triflyl phosphoramides; enantioselective pericyclic reactions





Autor: Felix E. Held, Dominik Grau and Svetlana B. Tsogoeva *

Fuente: http://mdpi.com/



DESCARGAR PDF




Documentos relacionados