Metathetical Redox Reaction of Diacetoxyiodoarenes and IodoarenesReportar como inadecuado




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Centre in Green Chemistry and Catalysis, Department of Chemistry, University of Sherbrooke, 2500 boul. de l’Université, Sherbrooke, QC J1K 2R1, Canada





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Academic Editors: Wesley Moran and Arantxa Rodríguez

Abstract The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between diacetoxyiodoarenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access diacetoxyiodoarenes. A computational study is provided to rationalize the results observed. View Full-Text

Keywords: hypervalent iodine; diacetoxyiodoarenes; metathesis hypervalent iodine; diacetoxyiodoarenes; metathesis





Autor: Antoine Jobin-Des Lauriers and Claude Y. Legault *

Fuente: http://mdpi.com/



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