The Role of Inclusion Binding Contributions for β-Cyclodextrin Polymers Cross-Linked with Divinyl Sulfone—A Comment on Morales-Sanfrutos et al. Entitled -Divinyl Sulfone Cross-Linked Cyclodextrin-Based Polymeric Materials: SyntReportar como inadecuado




The Role of Inclusion Binding Contributions for β-Cyclodextrin Polymers Cross-Linked with Divinyl Sulfone—A Comment on Morales-Sanfrutos et al. Entitled -Divinyl Sulfone Cross-Linked Cyclodextrin-Based Polymeric Materials: Synt - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

1

Department of Chemistry, College of Arts and Science, University of Saskatchewan, 110 Science Place, Saskatoon, SK S7N 5C9, Canada

2

Environmental Systems Engineering, Faculty of Engineering and Applied Science, University of Regina, 3737 Wascana Parkway, Regina, SK S4S0A2, Canada



These authors contributed equally to this work.





*

Author to whom correspondence should be addressed.



Academic Editor: Derek J. McPhee

Abstract This commentary reports on a recent scientific study reported in this journal cf. Molecules 2015, 203, 3565–3581. Some key scientific issues that require further explanation and clarification in the former article are as follows: i the relationship between the inclusion site accessibility and the level of cross-linking employed are brought into question for the case of α-CD and β-CD cross-linked adsorbent materials; ii the binding affinity of the CD-guest complexes were not related to the isotherm parameters for the CD-polymer-guest systems; iii the limited molecular level structural characterization of the cross-linked polymer materials; and iv the interpretation of the adsorption isotherm results by the authors. View Full-Text

Keywords: β-cyclodextrin; cross-linking; divinyl sulfone; adsorption; inclusion binding; polymer; phenolphthalein β-cyclodextrin; cross-linking; divinyl sulfone; adsorption; inclusion binding; polymer; phenolphthalein





Autor: Lee D. Wilson 1,†,* , Mohamed H. Mohamed 1,† and Dena W. McMartin 2

Fuente: http://mdpi.com/



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