Enzymatic Synthesis of Glucose-Based Fatty Acid Esters in Bisolvent Systems Containing Ionic Liquids or Deep Eutectic SolventsReportar como inadecuado


Enzymatic Synthesis of Glucose-Based Fatty Acid Esters in Bisolvent Systems Containing Ionic Liquids or Deep Eutectic Solvents


Enzymatic Synthesis of Glucose-Based Fatty Acid Esters in Bisolvent Systems Containing Ionic Liquids or Deep Eutectic Solvents - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

1

College of Life Sciences and Oceanography, Shenzhen Key Laboratory of Microbial Genetic Engineering, Shenzhen University, Shenzhen 518060, Guangdong, China

2

College of Life Sciences and oceanography, Shenzhen Key Laboratory of Marine Bioresources and Ecology, Shenzhen University, Shenzhen 518060, Guangdong, China

3

WestCHEM, Department of Pure & Applied Chemistry, University of Strathclyde, Glasgow G1 1XL, UK





*

Author to whom correspondence should be addressed.



Academic Editor: Hua Zhao

Abstract Sugar fatty acid esters SFAEs are biocompatible nonionic surfactants with broad applications in food, cosmetic, and pharmaceutical industries. They can be synthesized enzymatically with many advantages over their chemical synthesis. In this study, SFAE synthesis was investigated by using two reactions: 1 transesterification of glucose with fatty acid vinyl esters and 2 esterification of methyl glucoside with fatty acids, catalyzed by Lipozyme TLIM and Novozym 435 respectively. Fourteen ionic liquids ILs and 14 deep eutectic solvents DESs were screened as solvents, and the bisolvent system composed of 1-hexyl-3-methylimidazolium trifluoromethylsulfonate HMImTfO and 2-methyl-2-butanol 2M2B was the best for both reactions, yielding optimal productivities 769.6 and 397.5 µmol-h-g, respectively which are superior to those reported in the literature. Impacts of different reaction conditions were studied for both reactions. Response surface methodology RSM was employed to optimize the transesterification reaction. Results also demonstrated that as co-substrate, methyl glucoside yielded higher conversions than glucose, and that conversions increased with an increase in the chain length of the fatty acid moieties. DESs were poor solvents for the above reactions presumably due to their high viscosity and high polarity. View Full-Text

Keywords: sugar fatty acid esters; ionic liquids; deep eutectic solvents; lipase; alkyl glucoside; esterification; transesterification sugar fatty acid esters; ionic liquids; deep eutectic solvents; lipase; alkyl glucoside; esterification; transesterification





Autor: Kai-Hua Zhao 1, Yu-Zheng Cai 2, Xiao-Sheng Lin 1, Jun Xiong 2, Peter J. Halling 3 and Zhen Yang 1,*

Fuente: http://mdpi.com/



DESCARGAR PDF




Documentos relacionados