2 2 Photodimerization of Naphthylvinylpyridines through Cation-π Interactions in Acidic SolutionReportar como inadecuado


2   2 Photodimerization of Naphthylvinylpyridines through Cation-π Interactions in Acidic Solution


2 2 Photodimerization of Naphthylvinylpyridines through Cation-π Interactions in Acidic Solution - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

Department of Chemistry, Ochanomizu University, 2-1-1 Otsuka, Bunkyo-ku, Tokyo 112-8610, Japan





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Academic Editor: Shunichi Fukuzumi

Abstract Irradiation of E-4-2-2-naphthylvinylpyridine 1a and E-4-2-1-naphthylvinylpyridine 1b with a 250 W high-pressure mercury lamp in acidic solution afforded synHT dimers in high stereoselectivities. Similar results were obtained by visible light irradiation. On the other hand, when the reactions were carried out under neutral conditions, the stereoselectivities were very low, and the yields were decreased by visible light irradiation. Comparison of the UV-vis spectra between the acidic and the neutral conditions elucidated that the red shift was observed in acidic solutions. These results show that HCl plays essential roles not only in the preorientation of substrates through cation-π interactions, but also in the changes in the absorption properties of substrates that enable visible light reactions. View Full-Text

Keywords: cation-π interaction; 2 + 2 photodimerization; cyclobutane derivative; naphthylvinylpyridine; stereoselective reaction cation-π interaction; 2 + 2 photodimerization; cyclobutane derivative; naphthylvinylpyridine; stereoselective reaction





Autor: Shinji Yamada * and Yuka Nojiri

Fuente: http://mdpi.com/



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