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1

Department of Mathematical Analysis, Gent University, Galglaan 2, Gent B-9000, Belgium

2

Parks College of Engineering, Aviation and Technology, Saint Louis University, 3450 Lindell Blvd., Saint Louis, MO 63103, USA

3

Laboratory for Chemical Technology, Ghent University, Technologiepark 914, Gent B-9052, Belgium





*

Author to whom correspondence should be addressed.



Academic Editors: Michel Feidt, Daniel Tondeur, Jean-Noël Jaubert and Romain Privat

Abstract New patterns of steady-state chemical kinetics for continuously stirred-tank reactors CSTR have been found, i.e., intersections, maxima and coincidences, for two-step mechanism A↔B→C. There were found elegant analytical relationships for characteristics of these patterns space times, values of concentrations and rates allowing kinetic parameters to be easily determined. It was demonstrated that for the pair of species involved into the irreversible reaction B and C, the space time of their corresponding concentration dependence intersection is invariant and does not depend on the initial conditions of the system. Maps of patterns are presented for visualization of their combinations and ranking in space time, and values of concentration and rates. View Full-Text

Keywords: chemical kinetics; kinetic parameters; CSTR; patterns; two-step mechanism; intersections; coincidences; maxima chemical kinetics; kinetic parameters; CSTR; patterns; two-step mechanism; intersections; coincidences; maxima





Autor: Daniel Branco Pinto 1,* , Gregory Yablonsky 2, Guy B. Marin 3 and Denis Constales 1

Fuente: http://mdpi.com/



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