Unique Solutions to Hartree-Fock Equations for Closed Shell AtomsReportar como inadecuado



 Unique Solutions to Hartree-Fock Equations for Closed Shell Atoms


Unique Solutions to Hartree-Fock Equations for Closed Shell Atoms - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

Descargar gratis o leer online en formato PDF el libro: Unique Solutions to Hartree-Fock Equations for Closed Shell Atoms
In this paper we study the problem of uniqueness of solutions to the Hartree and Hartree-Fock equations of atoms. We show, for example, that the Hartree-Fock ground state of a closed shell atom is unique provided the atomic number $Z$ is sufficiently large compared to the number $N$ of electrons. More specifically, a two-electron atom with atomic number $Z\geq 35$ has a unique Hartree-Fock ground state given by two orbitals with opposite spins and identical spatial wave functions. This statement is wrong for some $Z1$, which exhibits a phase segregation.



Autor: M. Griesemer; F. Hantsch

Fuente: https://archive.org/



DESCARGAR PDF




Documentos relacionados