Vol 70: Poly3-3,5-di-nitro-benzoato-3O1:O1′:O32-hydroxido-2O:OcopperII.Report as inadecuate



 Vol 70: Poly3-3,5-di-nitro-benzoato-3O1:O1′:O32-hydroxido-2O:OcopperII.


Vol 70: Poly3-3,5-di-nitro-benzoato-3O1:O1′:O32-hydroxido-2O:OcopperII. - Download this document for free, or read online. Document in PDF available to download.

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This article is from Acta Crystallographica Section E: Structure Reports Online, volume 70.AbstractThe title complex, Cu{μ3-O2CC6H3NO22-3,5}μ-OHn, features zigzag chains in which successive pairs of CuII atoms are connected by OH bridges and bidentate carboxyl­ate ligands, leading to six-membered CuOOCOCu rings. The zigzag chains are connected into a three-dimensional architecture by Cu—Onitro bonds. The coordination geometry of the CuII atom is square-pyramidal, with the axial position occupied by the nitro O atom, which forms the longer Cu—O bond. Bifurcated hy­droxy–nitro O—H⋯O hydrogen bonds contribute to the stability of the crystal structure.



Author: Sinha, B.; Dey, G. C.; Sarkar, B.; Roy, A.; Ng, Seik Weng; Tiekink, Edward R. T.

Source: https://archive.org/







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