Technical Note: Determination of formaldehyde mixing ratios in polluted air with PTR-MS: laboratory experiments and field measurementsReportar como inadecuado




Technical Note: Determination of formaldehyde mixing ratios in polluted air with PTR-MS: laboratory experiments and field measurements - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

1 NIES - National Institute for Environmental Studies 2 JSPS Research Fellow 3 Hokkaido University 4 FRCGC - Frontier Research Center for Global Change 5 LAPC-NZC

Abstract : Formaldehyde HCHO, the most abundant carbonyl compound in the atmosphere, is generated as an intermediate product in the oxidation of nonmethane hydrocarbons. Proton transfer reaction mass spectrometry PTR-MS has the capability to detect HCHO from ion signals at m-z 31 with high time-resolution. However, the detection sensitivity is low compared to other detectable species, and is considerably affected by humidity, due to back reactions between protonated HCHO and water vapor prior to analysis. We performed a laboratory calibration of HCHO by PTR-MS and examined the detection sensitivity and humidity dependence at various field strengths. Subsequently, we deployed the PTR-MS instrument in a field campaign at Mount Tai in China in June 2006 to measure HCHO in various meteorological and photochemical conditions; we also conducted intercomparison measurements by Multi-Axis Differential Optical Absorption Spectroscopy MAX-DOAS. Correction of interference in the m-z 31 signals by fragments from proton transfer reactions with methyl hydroperoxide, methanol, and ethanol greatly improves agreement between the two methods, giving the correlation HCHOMAX-DOAS = 0.99±0.16 HCHOPTR-MS + 0.02±0.38, where error limits represent 95% confidence levels.





Autor: S. Inomata - H. Tanimoto - S. Kameyama - U. Tsunogai - H. Irie - Y. Kanaya - Z. Wang -

Fuente: https://hal.archives-ouvertes.fr/



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