The Optimization of Matrix Preparation Process and Performance Testing for Molten Carbonate Fuel CellReport as inadecuate

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Journal of Chemistry - Volume 2014 2014, Article ID 625893, 7 pages -

Research Article

State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China

Huaneng Clean Energy Research Institute, Beijing 100098, China

Received 27 February 2014; Accepted 26 March 2014; Published 23 April 2014

Academic Editor: Yixiang Shi

Copyright © 2014 Jian Cheng et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A key component in the molten carbonate fuel cell MCFC is electrolyte matrix, which provides both ionic conduction and gas sealing. The aim of this work is to investigate the effects of selected operating conditions on the performance of the matrix preparation. Slurries were prepared to produce matrices by the technique of tape casting. The characteristics of the slurries and matrices were examined by laser particle size analyzer, scanning electron microscopy, and BET surface area analyzer. The testing results revealed that a slurry composition with 40 wt.% lithium aluminate was the optimal formulation to produce a good matrix with a pore size distribution of 0.1–0.4 μm and porosity of 50 vol.%. Coarse and fine LiAlO2 particles were added in the matrix slurry to enhance the mechanical strength. Several green sheets were heated and pressed to enhance the bulk density to get a dense matrix of MCFC. Finally, a single MCFC was assembled and tested. The testing results showed the matrix with 40% solid loading gave the maximum discharge current of 20 A at 0.56 V.

Author: Jian Cheng, Liejin Guo, Shisen Xu, and Ruiyun Zhang



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