Syntheses and Spectroscopic Studies on Macrocyclic Complexes of DioxomolybdenumVI with Furil as PrecursorReportar como inadecuado




Syntheses and Spectroscopic Studies on Macrocyclic Complexes of DioxomolybdenumVI with Furil as Precursor - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

E-Journal of Chemistry - Volume 9 2012, Issue 2, Pages 497-503



Department of Chemistry, D.A-V College, Kanpur 208001, Uttar Pradesh, India

Department of Chemistry, North Eastern Regional Institute of Science and Technology NERIST, Nirjuli, Arunachal Pradesh, India

Department of Chemistry, M.G.P.G. College, Gorakhpur, Uttar Pradesh, India

Department of Chemistry, Rajendra College, Chapra, Bihar, India

Received 20 July 2011; Accepted 21 September 2011

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Due to their biological relevance, molybdenum catalyzed oxygen transfer reactions have great interest. With this view, some dioxomolybdenumVI complexes with general formula MoO2macacac2, where mac = tetraazamacrocyclic ligands derived from condensation of furil with 1,2-ethanediamine or 1,3-propanediamine and their reaction with β-diketones have been synthesized using dioxometal ion as kinetic template. The prepared complexes have been characterized by electrical conductance, elemental analyses, infrared and electronic data. All the dioxomoly-bdenumVI complexes have octahedral geometry with six coordination.





Autor: D. P. Rao, H. S. Yadav, A. K. Yadava, Sanjay Singh, and U. S. Yadav

Fuente: https://www.hindawi.com/



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