Synthesis and chemical reactivity of new zinc porphyrin diazoacetates catalyzed by ruthenium and iron porphyrinsReportar como inadecuado




Synthesis and chemical reactivity of new zinc porphyrin diazoacetates catalyzed by ruthenium and iron porphyrins - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

1 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : Zinc porphyrin diazoacetates were synthesized from the corresponding bromoacetates by treatment with N,N’-ditosylhydrazine in ∼70% yield. The transfer of carbenoids derived from the porphyrin diazo compounds catalyzed by metalloporphyrins Ru,Fe undergoes dimerization, cyclopropanation, N-H and S-H insertion reactions, respectively

Keywords : Ruthenium porphyrin Meso-phenyl-diazo-porphyrin ester Catalytic carbene transfer iron porphyrin





Autor: Daniel Carrié - Hassan Srour - Paul Le Maux - Gérard Simonneaux -

Fuente: https://hal.archives-ouvertes.fr/



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