Synthesis and Characterization of Rhodium Doped on TiO2-HCP for Enhanced Photocatalytic Performance on PentachlorophenolReportar como inadecuado




Synthesis and Characterization of Rhodium Doped on TiO2-HCP for Enhanced Photocatalytic Performance on Pentachlorophenol - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

Journal of Nanomaterials - Volume 2014 2014, Article ID 287493, 8 pages -

Research Article

Department of Chemistry, Vaal University of Technology, Private Bag x021, Vanderbijlpark 1900, South Africa

Department of Chemistry, University of Fort Hare, Private Bag x1314, Alice 5700, South Africa

Received 29 July 2014; Accepted 21 October 2014; Published 13 November 2014

Academic Editor: Mohamed Bououdina

Copyright © 2014 Saheed Olalekan Sanni and Omoruyi Gold Idemudia. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Visible-light-responsive material based on Rhodium doped on titanium dispersed on dealuminated clinoptilolite TiO2-HCP was synthesized via a combination of the sol-gel method and photoreductive deposition technique. The photocatalyst surface characterization, structural and optical properties were investigated by X-ray diffraction XRD, scanning electron microscopy SEM, energy-dispersive X-ray analysis EDAX, Fourier transform infrared spectroscopy FTIR, thermal gravimetric analysis TGA, and UV-visible spectra UV-VIS. Doping TiO2-HCP with Rh imparts a red shifting of the absorption band into the visible light region according to UV-VIS. The prepared composite materials were evaluated for their photocatalytic activities on pentachlorophenol PCP degradation under sunlight irradiation. The Rhodium doped TiO2-HCP exhibited enhanced photocatalytic activity and can be considered as a potential photocatalyst in wastewater treatment.





Autor: Saheed Olalekan Sanni and Omoruyi Gold Idemudia

Fuente: https://www.hindawi.com/



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