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Chinese Science Bulletin

, Volume 58, Issue 22, pp 2711–2718

First Online: 11 June 2013Received: 01 February 2013Accepted: 22 April 2013DOI: 10.1007-s11434-013-5892-1

Cite this article as: Yao, B., Sun, J., Qin, A. et al. Chin. Sci. Bull. 2013 58: 2711. doi:10.1007-s11434-013-5892-1


The research on using thiol-ene click reaction to synthesize sulfur-containing polymers with topological structures and advanced functional properties is a hot topic. However, the application of the thiol-yne reaction in the functional polymer preparation is limited and the thiol-yne click polymerization is to be further developed. In this review, we summarized recent research efforts on using thiol-yne click polymerization to synthesize polymers with topological structures. The sulfur-containing polymers were facilely prepared by photo- and thermo-initiated, amine-mediated, and transition-metal-catalyzed thiol-yne click polymerizations. These polymers are promising to be used as drug-delivery vehicles, high refractive index optical materials, photovoltaic materials, and biomaterials etc.

Keywordsthiol-yne click polymerization radical mechanism amine rhodium complex function This article is published with open access at

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Autor: BiCheng Yao - JingZhi Sun - AnJun Qin - Ben Zhong Tang


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