Synthesis, Characterization and Spectroscopic Studies of A Novel 2-E-2,4-dichlorophenyliminomethylphenol Schiff Base and Its Metal ComplexesReport as inadecuate




Synthesis, Characterization and Spectroscopic Studies of A Novel 2-E-2,4-dichlorophenyliminomethylphenol Schiff Base and Its Metal Complexes - Download this document for free, or read online. Document in PDF available to download.

E-Journal of Chemistry - Volume 9 2012, Issue 3, Pages 1543-1549

Department of Basic Science, College of Dentistry, University of Baghdad, Bab Al-Moazam, Baghdad, Iraq

Received 2 November 2011; Accepted 7 January 2012

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A novel Schiff base 2-{E-2,4-dichlorophenyliminomethyl}phenol LB was synthesized from the condensation reaction of 2,4-dichloroaniline with salicyladehyde in 1:1 ratio in the presence of glacial acetic acid as catalyst. Complexation reaction of this Schiff base with copper II, cobalt II as nitrate salts and with Rhodium III as chloride salt to produce three coordinate metal complexes, with a Schiff base: Metal ion ratio of 2:1. These compounds have been characterized by a variety of physico-chemical and spectroscopic techniques. The ligand and its metal complexes were expected to show an interesting bioactivity and cytotoxicity.





Author: Eman Turky Shamkhy and Isam Hussain T. Al-Karkhi

Source: https://www.hindawi.com/



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