Capillary electrophoresis with electrospray ionisation-mass spectrometry for the characterisation of degradation products in aged papersReport as inadecuate




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1 CRCC - Centre de Recherche pour la Conservation des Collections

Abstract : A methodology for capillary electrophoresis-electrospray ionisation mass spectrometry CE-ESI-MS was developed for the simultaneous analysis of degradation products from paper among two families of compounds: low molar mass aliphatic organic acids, and aromatic phenolic and furanic compounds. The work comprises the optimisation of the CE separation and the ESI-MS parameters for improved sensitivity with model compounds using two successive designs of experiments. The method was applied to the analysis of lignocellulosic paper at different stages of accelerated hygrothermal ageing. The compounds of interest were identified. Most of them could be quantified and several additional analytes were separated.

Keywords : Degradation Artificial ageing Cellulose Mass spectrometry Capillary electrophoresis Electrospray ionisation





Author: Anne-Laurence Dupont - Agathe Seemann - Bertrand Lavédrine -

Source: https://hal.archives-ouvertes.fr/



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