The Effects of Mixing, Reaction Rates, and Stoichiometry on Yield for Mixing Sensitive Reactions—Part II: Design ProtocolsReport as inadecuate

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International Journal of Chemical EngineeringVolume 2012 2012, Article ID 654321, 13 pages

Research Article

Department of Chemical and Materials Engineering, University of Alberta, 9107-116 Street, 7th Floor ECERF, Edmonton, AB, Canada T6G 2V4

Department of Mechanical Engineering, University of Alberta, 4-9 Mechanical Engineering Building, Edmonton, AB, Canada T6G 2G8

Received 29 April 2012; Revised 24 July 2012; Accepted 2 August 2012

Academic Editor: Shunsuke Hashimoto

Copyright © 2012 Syed Imran A. Shah et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Competitive-consecutive and competitive-parallel reactions are both mixing sensitive reactions where the yield of desired product depends on how fast the reactants are brought together. Recent experimental results have suggested that the magnitude of the mixing effect may depend strongly on the stoichiometry of the reactions. To investigate this, a 1D, dimensionless, reaction-diffusion model was developed at the micromixing scale, yielding a single general Damköhler number. Dimensionless reaction rate ratios were derived for both reaction schemes. A detailed investigation of the effects of initial mixing condition striation thickness, dimensionless reaction rate ratio, and reaction stoichiometry on the yield of desired product showed that the stoichiometry has a considerable effect on yield. All three variables were found to interact strongly. Model results for 12 stoichiometries are used to determine the mixing scale and relative rate ratio needed to achieve a specified yield for each reaction scheme. The results show that all three variables need to be considered when specifying reactors for mixing sensitive reactions.

Author: Syed Imran A. Shah, Larry W. Kostiuk, and Suzanne M. Kresta



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