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Reference: Marcin Sawicki, Angela Kwok, Matthew Tredwell et al., (2007). Single and double stereoselective fluorination of (E)-allylsilanes. Beilstein Journal of Organic Chemistry, 3, Article: 34.Citable link to this page:

 

Single and double stereoselective fluorination of (E)-allylsilanes

Abstract: Acyclic allylic monofluorides were prepared by electrophilic fluorination of branched (E)-allylsilanes with Selectfluor. These reactions proceeded with efficient transfer of chirality from the silylated to the fluorinated stereocentre. Upon double fluorination, an unsymmetrical ethyl syn-2.5-difluoroalk-3-enoic ester was prepared, the silyl group acting as an anti stereodirecting group for the two C-F bond forming events.

Publication status:PublishedPeer Review status:Peer reviewedVersion:Publisher's version Funder: European Community   Funder: Engineering and Physical Sciences Research Council   Funder: Pfizer   Notes:Citation: Sawicki, M. et al. (2007). 'Single and double stereoselective fluorination of (E)-allylsilanes', Beilstein Journal of Organic Chemistry, 3, 34. [Available at http://www.beilstein-journals.org/bjoc/home/home.htm]. © 2007 Sawicki et al; licensee Beilstein-Institut. This is an Open Access article under the terms of theCreative Commons Attribution License(http://creativecommons.org/licenses/by/2.0), whichpermits unrestricted use, distribution, and reproduction inany medium, provided the original work is properly cited.The license is subject to the Beilstein Journal of OrganicChemistry terms and conditions:(http://www.beilstein-journals.org/bjoc)

Bibliographic Details

Publisher: Beilstein Institut

Publisher Website: http://www.beilstein-institut.de/

Host: Beilstein Journal of Organic Chemistrysee more from them

Publication Website: http://www.beilstein-journals.org/bjoc/home/home.htm

Issue Date: 2007-10

Copyright Date: 2007

pages:Article: 34Identifiers

Doi: https://doi.org/10.1186/1860-5397-3-34

Urn: uuid:4a8ea25b-5dee-4c50-b619-57c5d38b7a0a Item Description

Type: Article: post-print;

Language: en

Version: Publisher's versionSubjects: Chemistry & allied sciences Tiny URL: ora:2773

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Autor: Marcin Sawicki - institutionUniversity of Oxford facultyMathematical, Physical and Life Sciences Division - Chemistry - Chemistry

Fuente: https://ora.ox.ac.uk/objects/uuid:4a8ea25b-5dee-4c50-b619-57c5d38b7a0a



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