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Reference: Hill, JA, Thompson, AL and Goodwin, AL, (2016). Dicyanometallates as model extended frameworks. Journal of the American Chemical Society, 138 (18), 5886-5896.Citable link to this page:


Dicyanometallates as model extended frameworks.

Abstract: We report the structures of eight new dicyanometallate frameworks containing molecular extra-framework cations. These systems include a number of hybrid inorganic−organic analogues of conventional ceramics, such as Ruddlesden−Popper phases and perovskites. The structure types adopted are rationalized in the broader context of all known dicyanometallate framework structures. We show that the structural diversity of this family can be understood in terms of (i) the charge and coordination preferences of the particular metal cation acting as framework node, and (ii) the size, shape, and extent of incorporation of extra-framework cations. In this way, we suggest that dicyanometallates form a particularly attractive model family of extended frameworks in which to explore the interplay between molecular degrees of freedom, framework topology, and supramolecular interactions.

Peer Review status:Peer reviewedPublication status:PublishedVersion:Publisher's version Funder: Engineering and Physical Sciences Research Council   Funder: European Research Council   Notes:© 2016 American Chemical Society. This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.

Bibliographic Details

Publisher: America Chemical Society

Publisher Website: http://www.acs.org/

Journal: Journal of the American Chemical Societysee more from them

Publication Website: http://pubs.acs.org/journal/jacsat

Issue Date: 2016-04


Urn: uuid:f9a5fca2-4c0a-4ae7-8882-3bb1f1d4b1b3

Source identifier: 619540

Eissn: 1520-5126

Doi: https://doi.org/10.1021/jacs.5b13446

Issn: 0002-7863 Item Description

Type: Journal article;

Language: eng

Version: Publisher's version Tiny URL: pubs:619540


Author: Hill, JA - institutionUniversity of Oxford Oxford, MPLS, Chemistry, Inorganic Chemistry - - - Thompson, AL - institutionUniversit

Source: https://ora.ox.ac.uk/objects/uuid:f9a5fca2-4c0a-4ae7-8882-3bb1f1d4b1b3


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