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Reference: J. C. Walker and A. Dudhia, (2011). Measurement from sun-synchronous orbit of a reaction rate controlling the diurnal NOx cycle in the stratosphere. Atmospheric Chemistry and Physics, 11 (10), 4861-4872.Citable link to this page:

 

Measurement from sun-synchronous orbit of a reaction rate controlling the diurnal NOx cycle in the stratosphere

Abstract: A reaction rate associated with the nighttime formation of an important diurnally varying species, N₂O₅, is determined from MIPAS-ENVISAT. During the day, photolysis of N₂O₅ in the stratosphere contributes to nitrogen-catalysed ozone destruction. However, at night concentrations of N₂O₅ increase, temporarily sequestering reactive NOₓ(NO and NO₂) in a natural cycle which regulates the majority of stratospheric ozone. In this paper, the reaction rate controlling the formation of N₂O₅ is determined from this instrument for the first time. The observed reaction rate is compared to the currently accepted rate determined from laboratory measurements. Good agreement is obtained between the observed and accepted experimental reaction rates within the error bars.

Publication status:PublishedPeer Review status:Peer reviewedVersion:Publisher's version Funder: Natural Environment Research Council   Notes:Citation: Walker, J.C. & Dudhia, A. (2011). 'Measurement from sun-synchronous orbit of a reaction rate controlling the diurnal NOx cycle in the stratosphere', Atmospheric Chemistry and Physics, 11(10), 4861-4872. [Available at http://www.atmos-chem-phys.net/11/4861/2011/]. © Authors 2011. This work is distributed under the terms of the Creative Commons Attribution 3.0 Licence (http://creativecommons.org/licenses/by/3.0/). This permits the copying, distribution, transmission and adaption of the work, provided the original authors are credited. For any reuse or distribution, you must make clear to others the license terms of this work. These conditions may be waived if you get permission from the copyright holder.

Bibliographic Details

Publisher: Copernicus Publications

Publisher Website: http://publications.copernicus.org/

Host: Atmospheric Chemistry and Physicssee more from them

Publication Website: http://www.atmospheric-chemistry-and-physics.net/home.html

Issue Date: 2011-May

Copyright Date: 2011

pages:4861-4872Identifiers

Doi: https://doi.org/10.5194/acp-11-4861-2011

Issn: 1680-7316

Eissn: 1680-7324

Urn: uuid:fdcf2525-666a-405e-9600-fb697cf38115 Item Description

Type: Article: post-print;

Language: en

Version: Publisher's versionKeywords: ozoneSubjects: Physics Atmospheric,Oceanic,and Planetary physics Tiny URL: ora:5705

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Autor: J. C. Walker - institutionUniversity of Oxford facultyMathematical,Physical and Life Sciences Division - Physics - Atmospheric,Oc

Fuente: https://ora.ox.ac.uk/objects/uuid:fdcf2525-666a-405e-9600-fb697cf38115



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