Electromotive Force Measurements in Liquid Li-Si AlloysReport as inadecuate

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Journal of Phase Equilibria and Diffusion

, Volume 33, Issue 5, pp 352–356

First Online: 19 July 2012Received: 07 February 2012Revised: 04 May 2012


Electromotive force measurements on the Li-Si system were initiated by the concentration cell method with an LiCl-LiFeut electrolyte and the Bi,Li3Bil + Li3Bis two phase alloy as a reference electrode. The measurements are carried out in the temperature range between 880 and 1020 K for liquid alloys containing 0.57, 0.61, 0.815, and 0.85 mole fractions of Li. The activities of Li in liquid Li-Si alloys determined in this work are compared with the activities calculated from the set of thermodynamic parameters optimized by Braga et al. Present results are in reasonable agreement with calculated data.

Keywordsactivity electromotive force emf liquid Li-Si system  Download fulltext PDF

Author: Przemysław Fima - Adam Dębski - Władysław Gąsior

Source: https://link.springer.com/

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