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Transition Metal Chemistry

, Volume 35, Issue 7, pp 821–827

First Online: 28 July 2010Received: 14 May 2010Accepted: 08 July 2010

Abstract

CobaltII tri-tert-butoxysilanethiolates with 2,5-dimethylpyridine, 3,4-dimethylpyridine and 3,5- dimethylpyridine co-ligands have been synthesized by reaction of bimetallic Co{μ-SSiOBu3}{SSiOBu3}NH32 with the appropriate pyridines. The complexes were characterized by elemental analysis, single-crystal X-ray structure determination, IR and UV–Vis spectroscopy. These complexes are tetra- or penta-coordinated with CoN2S2 and CoNO2S2 cores, respectively.

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Autor: Agnieszka Pladzyk - Joanna Olszewska - Katarzyna Baranowska - Anna Maria Dziurzyńska

Fuente: https://link.springer.com/







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