Red and Blue Compounds Formed from CopperII Bromide and the Ligand 7-Isobutyl-5-methyl-1,2,4triazolo1,5-apyrimidine: Synthesis, Spectroscopy and Single-Crystal StructuresReportar como inadecuado




Red and Blue Compounds Formed from CopperII Bromide and the Ligand 7-Isobutyl-5-methyl-1,2,4triazolo1,5-apyrimidine: Synthesis, Spectroscopy and Single-Crystal Structures - Descarga este documento en PDF. Documentación en PDF para descargar gratis. Disponible también para leer online.

Journal of Chemical Crystallography

, Volume 40, Issue 11, pp 1006–1010

First Online: 29 May 2010Received: 04 November 2009Accepted: 13 May 2010

AbstractTwo newly synthesized coordination compounds copperII bromide with the ligand 7-isobutyl-5-methyl1,2,4triazolo1,5-apyrimidine abbreviated as ibmtp are presented, together with their 3D crystal structure and spectroscopic and magnetic properties. The compounds are CuBr2ibmtp2 1 red crystals and CuBribmtp4BrH2O3 2 blue crystals. In 1 the Cuii ion is present in a distorted tetrahedral environment, while in 2 the Cuii ion has a square pyramidal geometry. These crystal structures are also the first ones reported with the ligand ibmtp.

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AbstractCoordination compounds CuBr2ibmtp2 red and CuBribmtp4BrH2O3 blue, with ibmtp = 7-isobutyl-5-methyl1,2,4triazolo1,5-apyrimidine are presented. The CuII is present in distorted tetrahedral, and square pyramidal geometries, respectively, and binds at N3.Open image in new windowKeywordsCopper Bromide Triazolopyrimidine Electronic supplementary materialThe online version of this article doi:10.1007-s10870-010-9785-8 contains supplementary material, which is available to authorized users.

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Autor: Esref Günay - Ilpo Mutikainen - Urho Turpeinen - Gerard A. van Albada - Jaap G. Haasnoot - Jan Reedijk

Fuente: https://link.springer.com/







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